cerium(III) chloride

Recent progress in cerium(III) chloride promoted organic reactions and their applications to or- ganic synthesis were reviewed in this paper with the focus on carbon-carbon and carbon-heteroatom bonds formation reactions and selective deprotection reactions.

综述了近年来三氯化铈促进的多种有机反应及其在有机合成中的应用,其中重点讨论了三氯化铈促进下的碳—碳原子键、碳—杂原子键的形成反应以及多种保护基团的选择性脱保护反应等。

This thesis aims to study two kinds of ketones(PhCOFc,FcCOFc) react with some organometallic reagents(CH_3MgI,CH_3CH_2MgBr,(CH_3)_2CHMgBr,CH_3(CH_2)_3MgBr, PhMgBr,FcLi) in the presence of anhydrous cerium(Ⅲ) chloride or not.

本文研究了在无水三氯化铈存在下,两种位阻较大的二茂铁酮(PhCOFc,FcCOFc)与一些有机金属试剂(CH_3MgI,CH_3CH_2MgBr,(CH_3)_2CHMgBr,CH_3(CH_2)_3MgBr,PhMgBr,FcLi)的反应,并与三氯化铈不存在的反应做比较;同时讨论了卤代烷用量对反应产率的影响。

The Synthetic of CpCeCl3·nTHF(Cp=Cyclopentadienyl,n=0,1,2,3,THF=Tetrahdrofuran);

环戊二烯基三氯化铈的合成