sulfocarbonic acid,thiocarbonic acid

Taking sodium thiocarbonate as raw material,the precursor HgCS_3 is synthesized by liquid phase reaction at room temperature,then HgCS_3 is decomposed in the autoclave at proper temperature and pressure to form nanometer HgS,whose composition,size and shape are characterized by XRD and TEM.

以硫代碳酸钠为原料,用室温液相反应合成出前驱物硫代碳酸汞,置于高压釜中,在适当温度和压力下分解,即得纳米硫化汞。

A New Way to Formation of Perthiocarbonate Ligand── Synthesis and Crystal Structures of [Me_4N]_n[Cu(CS_4)]_n(Ⅰ) and [Me_4N]_4[Cu_4(CS_4)_4](Ⅱ);

过硫代碳酸配体[CS_4]~(2-)生成的新方法──[Me_4N]_n[Cu(CS_4)]_n(I)和[Me_4N]_4[Cu_4(CS_4)_4](Ⅱ)的合成与晶体结构