enantiosymmetric polymerization

Optically active polymers with one-handed helical conformations can be obtained through asymmetric polymerization of the above two monomers in the presence of chiral ligands.

含有大位阻基团的1,1-双取代α,β-不饱和酯,诸如甲基丙烯酸三苯甲酯(TrMA)、甲基丙烯酸邻甲苯基二苯基甲酯(DPIMA),在不对称聚合反应中,能够形成具有单手螺旋构象的旋光性聚合物。