trialkylaluminum compounds

New alkylaluminum complexes supported by β-aminoalcohol ligands were prepared through a series of reactions by N,N-dimetyl-toluidine,t-BuCl,benzophenone and trialkylaluminum in a purified nitrogen atmosphere and were characterized by IR,EA,and NMR(1H,13C).

利用该类烷基铝配合物在不同的溶剂、温度下催化己内酯聚合,实验表明对己内酯开环聚合有着较高的催化活性,其中以二氯甲烷为溶剂在回流条件下聚合性能最高。

Influence of trialkylaluminum on properties of methylaluminoxane;

三烷基铝对甲基铝氧烷性能的影响

Study on Kinetic of the Displacement Reaction of Trialkylaluminum with Ethylene Catalyzed by Cobalt Complexes;

钴配合物催化的乙烯与三烷基铝置换反应动力学研究(英文)